منابع مشابه
Kinetics and morphologies of viscoelastic phase separation.
In this paper, the effects of relaxational bulk modulus and the average composition of polymers on the viscoelastic phase separation are investigated in detail. It is found that there are two typical morphologies, i.e., moving droplet phase and phase inversion, and the relaxation of the dynamical asymmetry and the amplification of the concentration fluctuation are responsible for the appearance...
متن کاملViscoelastic phase separation in shear flow.
We numerically investigate viscoelastic phase separation in polymer solutions under shear using a time-dependent Ginzburg-Landau model. The gross variables in our model are the polymer volume fraction and a conformation tensor. The latter represents chain deformations and relaxes slowly on the rheological time giving rise to a large viscoelastic stress. The polymer and the solvent obey two-flui...
متن کاملPolymerization-induced viscoelastic phase separation in polyethersulfone-modified epoxy systems.
The polymerization-induced phase-separation process of polyethersulfone (PES)-modified epoxy systems was monitored in situ continuously on a single sample throughout the entire curing process by using optical microscopes, time-resolved light scattering (TRLS), scanning electronic microscopes (SEM), and a rheometry instrument. At specific PES content a viscoelastic transformation process of phas...
متن کاملTwo-phase viscoelastic jetting
A coupled finite difference algorithm on rectangular grids is developed for viscoelastic ink ejection simulations. The ink is modeled by the Oldroyd-B viscoelastic fluid model. The coupled algorithm seamlessly incorporates several things: (1) a coupled level set-projection method for incompressible immiscible two-phase fluid flows; (2) a higher-order Godunov type algorithm for the convection te...
متن کاملPhase separation in the Hubbard model.
The Hartree-Fock ground-state phase diagram of the one-dimensional Hubbard model is calculated in the μ−U plane, restricted to phases with no charge density modulation. This allows antiferromagnetism, saturated ferromagnetism, spiral spin density waves and a collinear structure with unit cell ↑↑↓↓. The spiral phase is unstable against phase separation near quarter-, halfand three-quarter-fillin...
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ژورنال
عنوان ژورنال: Physical Review E
سال: 1997
ISSN: 1063-651X,1095-3787
DOI: 10.1103/physreve.56.4451